Print Window
Click on Tools and then on Internet Options

Under General at My Internet e-mail address is: type your email address

Click on Receiving (POP3) at the top and then on add

Click on New

Enter the POP3 Server Hostname, Username and Password as supplied by your ISP and click OK

Highlight the definition, in this case POP3, and click on select

You should now see POP3 at Check these POP3 hosts for mail

Click on Sending (SMTP). Click on Add

Click on New

Enter your SMTP Server Hostname as provided by your ISP and click OK

Highlight the definition, in this case SMTP, and click on select

You should now see SMTP at Send mail using these SMTP hosts and click OK